Isolation of a Cyclic (Alkyl)(amino)germylene.
نویسندگان
چکیده
A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC₃N five-membered ring skeleton. By reducing 2 with KC₈, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N₂O and S₈, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.
منابع مشابه
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ورودعنوان ژورنال:
- Molecules
دوره 21 8 شماره
صفحات -
تاریخ انتشار 2016